| 1 | 2023 | Bahrain | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 16 | 12 | |
| 2023 | Bahrain | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 15 | 10 | |
| 2 | 2023 | Saudi Arabia | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 20 | 16 | |
| 2023 | Saudi Arabia | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 17 | ab | Brakes |
| 3 | 2023 | Australia | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 18 | 16 | Collision |
| 2023 | Australia | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 8 | ab | Accident |
| 4 | 2023 | Azerbaijan | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 14 | 16 | |
| 2023 | Azerbaijan | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 12 | 12 | |
| 5 | 2023 | Miami | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 20 | 20 | |
| 2023 | Miami | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 11 | 14 | |
| 6 | 2023 | Monaco | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 16 | 18 | |
| 2023 | Monaco | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 13 | 14 | |
| 7 | 2023 | Spain | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 20 | 20 | |
| 2023 | Spain | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 18 | 16 | |
| 8 | 2023 | Canada | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 18 | ab | Oil leak |
| 2023 | Canada | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 9 | 7 | |
| 9 | 2023 | Austria | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 18 | 13 | |
| 2023 | Austria | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 10 | 11 | |
| 10 | 2023 | Britain | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 14 | 11 | |
| 2023 | Britain | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 8 | 8 | |
| 11 | 2023 | Hungary | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 20 | 18 | Withdrew |
| 2023 | Hungary | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 16 | 11 | |
| 12 | 2023 | Belgium | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 18 | 17 | |
| 2023 | Belgium | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 15 | 14 | |
| 13 | 2023 | Netherlands | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 10 | ab | Accident |
| 2023 | Netherlands | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 4 | 8 | |
| 14 | 2023 | Italy | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 15 | 13 | |
| 2023 | Italy | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 6 | 7 | |
| 15 | 2023 | Singapore | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 18 | 14 | |
| 2023 | Singapore | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 14 | 11 | |
| 16 | 2023 | Japan | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 20 | ab | Undertray |
| 2023 | Japan | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 13 | ab | Undertray |
| 17 | 2023 | Qatar | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 15 | ab | Exhausted |
| 2023 | Qatar | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 13 | 13 | |
| 18 | 2023 | USA | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 16 | 10 | |
| 2023 | USA | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 15 | 9 | |
| 19 | 2023 | Mexico City | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 19 | 16 | Fuel pump |
| 2023 | Mexico City | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 14 | 9 | |
| 20 | 2023 | São Paulo | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 19 | 11 | |
| 2023 | São Paulo | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 13 | ab | Collision |
| 21 | 2023 | Las Vegas | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 6 | 16 | |
| 2023 | Las Vegas | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 5 | 12 | |
| 22 | 2023 | Abu Dhabi | Williams Racing | 2 | SARGEANT Logan | Mercedes M14 E Performance V6 t h | Pirelli | 20 | 16 | |
| 2023 | Abu Dhabi | Williams Racing | 23 | ALBON Alexander | Mercedes M14 E Performance V6 t h | Pirelli | 14 | 14 | |
| 2023 | Abu Dhabi | Williams Racing | 45 | O'SULLIVAN Zak | Mercedes M14 E Performance V6 t h | Pirelli | | t | Third driver |